Questions
Question 1
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What quantity must be integrated to find the entropy change between two equilibrium states?
Question 2
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For a reversible heat transfer \(Q_{\mathrm{rev}}\) at constant temperature \(T\), what is \(\Delta S\)?
Question 3
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A thermal reservoir at \(300\,\mathrm{K}\) absorbs \(1200\,\mathrm{J}\) of heat. Find its entropy change.
Question 4
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A thermal reservoir at \(500\,\mathrm{K}\) releases \(750\,\mathrm{J}\) of heat. Find its entropy change.
Question 5
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Find the entropy change when \(0.020\,\mathrm{kg}\) of ice melts reversibly at \(273\,\mathrm{K}\). Use \(L_f=3.34\times10^5\,\mathrm{J\,kg^{-1}}\).
Question 6
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Find the entropy change of \(0.010\,\mathrm{kg}\) of water when it vaporizes reversibly at \(373\,\mathrm{K}\). Use \(L_v=2.26\times10^6\,\mathrm{J\,kg^{-1}}\).
Question 7
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One mole of ideal gas expands isothermally from \(V_i\) to \(2V_i\). Find \(\Delta S\).
Question 8
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Two moles of ideal gas are compressed isothermally from \(3.0\,\mathrm{L}\) to \(1.0\,\mathrm{L}\). Find \(\Delta S\).
Question 9
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A body with constant heat capacity \(C=80\,\mathrm{J\,K^{-1}}\) is warmed reversibly from \(300\,\mathrm{K}\) to \(360\,\mathrm{K}\). Find \(\Delta S\).
Question 10
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A monatomic ideal gas with \(n=2.0\,\mathrm{mol}\) is heated at constant volume from \(300\,\mathrm{K}\) to \(450\,\mathrm{K}\). Find \(\Delta S\). Use \(C_V=3R/2\).
Question 11
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A monatomic ideal gas with \(n=1.0\,\mathrm{mol}\) is heated at constant pressure from \(300\,\mathrm{K}\) to \(600\,\mathrm{K}\). Find \(\Delta S\). Use \(C_P=5R/2\).
Question 12
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A \(500\,\mathrm{J}\) heat transfer occurs directly from a \(400\,\mathrm{K}\) reservoir to a \(250\,\mathrm{K}\) reservoir. Find \(\Delta S_{\mathrm{univ}}\) and decide whether the process is reversible.
Question 13
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An ideal gas freely expands into vacuum in an insulated container until its volume doubles. For \(n=1.5\,\mathrm{mol}\), find \(Q\), \(W\), \(\Delta U\), and \(\Delta S\).
Question 14
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A system undergoes a process with \(\Delta S_{\mathrm{sys}}=-18\,\mathrm{J\,K^{-1}}\). It dumps heat into a large reservoir at \(300\,\mathrm{K}\). What is the minimum heat the reservoir must receive for the process to be allowed by the second law?
Question 15
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An ideal gas changes from \((T_i,V_i)\) to \((2T_i,3V_i)\). Derive \(\Delta S\) in terms of \(n\), \(C_V\), and \(R\).
Question 16
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A hot reservoir at \(T_h\) transfers heat \(Q\) directly to a cold reservoir at \(T_c\), where \(T_h>T_c\). Derive \(\Delta S_{\mathrm{univ}}\) and explain why the result is positive.
Question 17
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Two identical objects of heat capacity \(C\) are initially at \(T_h\) and \(T_c\), with \(T_h>T_c\). They are placed in thermal contact and isolated from the surroundings. Derive the final temperature and the total entropy change, assuming constant \(C\).
Question 18
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An ideal gas has the same initial and final states for two processes: reversible isothermal expansion from \(V_i\) to \(V_f\), and free expansion into vacuum from \(V_i\) to \(V_f\). Compare \(Q\), \(W\), \(\Delta U\), and \(\Delta S\) for the two processes, and explain what this shows about entropy.
Question 19
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A process takes an ideal gas from state \(i\) to state \(f\). You know \(T_i,T_f,V_i,V_f,n,\) and \(C_V\), but the actual path is irreversible. Explain how to calculate \(\Delta S\), and derive the expression you would use.
Question 20
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A system interacts only with a single thermal reservoir at temperature \(T_0\). During a cycle, the system returns to its initial state and receives net heat \(Q\) from the reservoir. Use entropy to determine the allowed sign of \(Q\), and interpret the result physically.