AcademyPhotons

Academy

Wave-Particle Duality

Level 1 - Physics topic page in Photons.

Principle

Quantum objects show both wave-like and particle-like behavior. Light travels and interferes as a wave, but exchanges energy and momentum in discrete photon packets.

Matter also has wave behavior, described by the de Broglie wavelength.

Notation

\(E\)
particle or photon energy
\(\mathrm{J,\;eV}\)
\(p\)
momentum magnitude
\(\mathrm{kg\,m\,s^{-1}}\)
\(\lambda\)
wavelength
\(\mathrm{m}\)
\(f\)
frequency
\(\mathrm{s^{-1}}\)
\(h\)
Planck constant
\(\mathrm{J\,s}\)
\(K\)
non-relativistic kinetic energy
\(\mathrm{J}\)

Method

Derivation 1: Photon relations

For light, wave variables and particle variables are linked by Planck's constant.

Photon energy
\[E=hf\]
Photon momentum
\[p=\frac{h}{\lambda}\]

Derivation 2: Matter waves

A particle with momentum \(p\) has de Broglie wavelength.

de Broglie wavelength
\[\lambda=\frac{h}{p}\]
Non-relativistic momentum
\[p=\sqrt{2mK}\]

Derivation 3: Interpret experiments

Interference and diffraction reveal wave behavior. Localized detection and energy transfer reveal particle behavior.

Photoelectric photon energy
\[K_{\max}=hf-\phi\]
Diffraction scale
\[a\sin\theta\sim\lambda\]

Rules

Photon energy
\[E=hf\]
Photon momentum
\[p=\frac{h}{\lambda}\]
de Broglie wavelength
\[\lambda=\frac{h}{p}\]
Non-relativistic momentum
\[p=\sqrt{2mK}\]

Examples

Question
Find the photon momentum for
\[\lambda=500\,\mathrm{nm}\]
Answer
\[p=\frac{h}{\lambda}=\frac{6.63\times10^{-34}}{500\times10^{-9}}=1.33\times10^{-27}\,\mathrm{kg\,m\,s^{-1}}\]

Checks

  • Wave-particle duality does not mean a classical wave plus a classical particle at the same time.
  • The observed behavior depends on the measurement setup.
  • Interference can build up one particle at a time.
  • A smaller momentum means a larger de Broglie wavelength.